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The extracellular L-cysteine/L-cystine redox balance, and thus the synthesis of GSH, is finely regulated by the intracellular conversion of L-cystine into L-cysteine (10), and its impairment is related to oxidative stress and other pathological disorders

The biosynthesis of its precursor, glucoraphanin, is a paradigm of specialized metabolism, orchestrated by a conserved pathway that transforms the primary amino acid L-methionine into a potent defense compound ( Figure 1 )

However, when GPX4 is deficient or inactive, LOOHs will accumulate to a high level, leading to catastrophic membrane damage

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